By Janine Hughes


Nearly four decades ago a fledgling industry emerged that specializes in developing advanced methods of separating the individual components of gases. Today, those efforts have become an important factor in driving production costs lower by using less energy, and eliminating some types of environmental pollution. Early experiments in diffusion led to practical industrial applications today, and gas separation membrane technology is rapidly expanding.

The primary impact is in hydrogen separation in petrochemical plants or ammonia production facilities, in removing nitrogen from air, separating water vapor and carbon dioxide from natural gas during refining, and the removal of organic vapor from air or other gas mixtures. Various types of filters have separated liquid components successfully, and the same general filtering principles are being applied to industrial gases.

The newer processes have become especially significant within the petrochemical industry, and are now cost-competitive with other methods. Extracting various valuable components from natural gas has been historically expensive, but can now be removed quickly and efficiently without incurring extra costs. The associated equipment is relatively simple to use, and is considered low-maintenance. Related sales are in the multi-miillion dollar range.

The key to efficient and successful operation is the membrane itself. Construction materials may vary, but all form a specific type of barrier that only allows certain types of molecules to pass through. These devices in general allow gases, vapors and liquids to be separated at varying speeds, completely blocking out some of the components. Some are slowed down considerably, while others are unable to gain access.

Polymers are the most common types of plastic used to make these filters. The material can be fashioned into hollow fibers that create a comparatively large surface area when combined. Most are produced using existing raw materials and currently available technology, and the cost of making them is within competitive range. These advantages have allowed them to become important in various types of industrial production.

The process can be used continuously, and generally uses a high-pressure stream of the gas mixture. It is forced to pass by the membrane, and certain types of molecules are released on the other side, while others are prevented from passing. Those that cannot can be retained as well, and the efficiency of this method is determined by the properties of the permeable barrier.

The most attractive advantage associated with this process is the removal of a major step in production that is characteristic of more established technologies, which include cryogenic distillation of air, amine absorption, or basic condensation. The older processes all include a phase where gas converts to liquid, a step that necessarily uses more energy and is costlier. Membranes eliminate that effort at significant cost savings.

Because the petrochemical industry must continuously find new ways to produce fuels and other products in a way that makes the best use of existing raw materials, the future of this type of technology is open-ended. New applications can be applied to growth areas such as the removal of hydrocarbons from hydrogen or methane, or propylene from propane. Expansion in the next two decades promises to be continuous.




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